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1 article(s) from Ribagorda, María

Control over molecular motion using the cis–trans photoisomerization of the azo group

Estíbaliz Merino and
María Ribagorda

Beilstein J. Org. Chem. 2012, 8, 1071–1090, doi:10.3762/bjoc.8.119

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Graphical Abstract

Figure 1: Photoisomerization process of azobenzene.

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Figure 2: Representative example of an UV spectrum of an azocompound of the azobenzene type (blue line: trans...

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Figure 3: Mechanistic proposals for the isomerization of azobenzenes.

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Figure 4: Representation of the photocontrol of a K⁺ channel in the cellular membrane based on the isomerizat...

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Figure 5: (a) MAG interaction with iGluR; (b) photocontrol of the opening of the ion channel by trans–cis iso...

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Figure 6: Photocontrol of the structure of the α-helix in the polypeptide azoderivative 2. Reprinted (adapted...

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Figure 7: Recognition of a guanidinium ion by a cis,cis-bis-azo derivative 3.

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Figure 8: Recognition of cesium ions by cis-azo derivative 4.

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Figure 9: Photocontrolled formation of an inclusion complex of cyclodextrin trans-azo 5+6.

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Figure 10: Pseudorotaxane-based molecular machine.

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Figure 11: Molecular hinge. Reprinted (adapted) with permission from Org. Lett. 2004, 6, 2595–2598. Copyright ...

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Figure 12: Molecular threader. Reprinted (adapted) with permission from Acc. Chem. Res. 2001, 34, 445–455. Cop...

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Figure 13: Molecular scissors based on azobenzene 12. Reprinted (adapted) with permission from J. Am. Chem. So...

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Figure 14: Molecular pedals. Reprinted by permission from Macmillan Publishers Ltd: Nature, 2006, 440, 512–515...

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Figure 15: Design of nanovehicles based on azo structures. Reprinted (adapted) with permission from Org. Lett. ...

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Figure 16: Light-activated mesostructured silica nanoparticles (LAMs).

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Figure 17: Molecular lift.

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Figure 18: Conformational considerations in mono-ortho-substituted azobenzenes.

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Scheme 1: Synthesis and photoisomerization of sulfinyl azobenzenes. Reprinted (adapted) with permission from ...

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Figure 19: Photoisomerization of azocompound 22 and its application as a photobase catalyst.

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Figure 20: Effect of irradiation with linearly polarized light on azo-LCEs. Reprinted by permission from Macmi...

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Figure 21: Chemically and photochemically triggered memory switching cycle of the [2]rotaxane 25.

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Figure 22: Unidirectional photoisomerization process of the azobenzene 26.

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Album

Review

Published 12 Jul 2012

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